This paper adopts the panel data of 30 provinces in China from 2000 to 2014 to construct a dynamic panel data model, and uses system generalized moment estimation method to study the influences of producer services agglomeration on the growth of green total factor productivity. The main conclusions are: First, the growth of green total factor productivity has a strong lag effect and is significantly affected by the growth of green total factor productivity in the previous period. Second, the agglomeration of producer services has the effect of promoting the growth of green total factor productivity. Human capital, R&D investment, infrastructure, and opening also play a positive role in promoting the growth of green total factor productivity. Third, the influence of agglomeration of producer services on the growth of green total factor productivity has a nonlinear characteristic, which is in accordance with the “Williamson hypothesis”. There is a clear regional difference in promoting the growth of green total factor productivity in the agglomeration of productive service industries,the promotion is only significant in the central region.Fourth, there is a clear industry difference in promoting the growth of green total factor productivity in the agglomeration of productive service industries. The most significant ones are the transportation, warehousing and postal services, and the financial sector; followed by information transmission, software and technical services, scientific research and technical services.