Through analysis and thinking of studying of the present core competition mechanics, the text propost that the enterprise's values are the first key element in enterprise's core competitiveness system. And from different angle to seek key inherent law between the enterprise values and enterprise competitiveness, thus proved effectively enterprise's values are getting army's strength of enterprise's key competitiveness, it is the final energy source that supports enterprise's competition advantage continuously. On this basis, this text manage from values angle to propose the cultivation thought of the enterprise core countermeasure, strive to provide the valued reference suggestion for the practice of the core competitiveness of Chinese enterprises.